Aye. Here is a little tutorial for photoshop mlp vectors, the basics and how to start off.
The tools you gonna use are those;
Pen tool, convert point/direct point tool, shape tool, text tool.
When you get photoshop, the pen tool bar should look like this:
To make vectors, be sure that the 'PATH' button is not path. To change that, click it.
You should click the shape option mode to vector.
The shape bar:
SOME BEHIND THE SCENES WORK